arXiv:2610.08493v1 Announce Type: new Abstract: In this paper, we propose an explainable artificial intelligence framework to explain the solution of optimal control problems predicted with graph neural networks (GNNs). The proposed approach first trains a GNN that predicts the solution of the optimal control problem for a given instance represented as a graph. Given the trained GNN, we use explainable AI algorithms to identify variables, constraints, variable-constraint connections, and parameters, i.e., nodes, edges, and features in the graph representation of the optimal control problem, that affect the prediction of the optimal solution the most. We apply the proposed approach to a case study regarding the optimal control of a continuous stirred tank reactor. First, the results show that the GNN model can accurately predict the optimal values of the manipulated variables. Application of explainable AI algorithms reveals equality and inequality constraints that are the most important for predicting the optimal solution. The inequality constraints correspond to ramping constraints, some of which are active at the optimal solution.