arXiv:2506.19957v4 Announce Type: replace Abstract: Radio-frequency simultaneous localization and mapping (RF-SLAM) methods jointly infer the position of mobile transmitters and receivers in wireless networks, together with a geometric map of the propagation environment. An inferred map of specular surfaces can be used to exploit non-line-of-sight components of the multipath channel to increase robustness, bypass obstructions, and improve overall communication and positioning performance. While performance bounds for user location are well established, the literature lacks performance bounds for map information. This paper derives the mapping error bound (MEB), i.e., the posterior Cram\'er-Rao lower bound on the position and orientation of specular surfaces, for RF-SLAM. In particular, we consider a very general scenario with single- and double-bounce reflections, as well as distributed anchors. We demonstrate numerically that a state-of-the-art RF-SLAM algorithm asymptotically converges to this MEB. The bounds assess not only the localization (position and orientation) but also the mapping performance of RF-SLAM algorithms in terms of global features.